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orbital hybridisation
In chemistry, hybridisation (or hybridization) is the concept of mixing atomic orbitals into new ''hybrid orbitals'' (with different energies, shapes, etc., than the component atomic orbitals) suitable for the pairing of electrons to form chemical bonds in valence bond theory. Hybrid orbitals are very useful in the explanation of molecular geometry and atomic bonding properties. Although sometimes taught together with the valence shell electron-pair repulsion (VSEPR) theory, valence bond and hybridisation are in fact not related to the VSEPR model.
== History ==
Chemist Linus Pauling first developed the hybridisation theory in 1931 in order to explain the structure of simple molecules such as methane (CH4) using atomic orbitals. Pauling pointed out that a carbon atom forms four bonds by using one s and three p orbitals, so that "it might be inferred" that a carbon atom would form three bonds at right angles (using p orbitals) and a fourth weaker bond using the s orbital in some arbitrary direction. In reality however, methane has four bonds of equivalent strength separated by the tetrahedral bond angle of 109.5°. Pauling explained this by supposing that in the presence of four hydrogen atoms, the s and p orbitals form four equivalent combinations or ''hybrid'' orbitals, each denoted by sp3 to indicate its composition, which are directed along the four C-H bonds.〔L. Pauling ''The Nature of the Chemical Bond'' (3rd ed., Oxford University Press 1960) p.111–120.〕 This concept was developed for such simple chemical systems, but the approach was later applied more widely, and today it is considered an effective heuristic for rationalising the structures of organic compounds. It gives a simple orbital picture equivalent to Lewis structures. Hybridisation theory finds its use mainly in organic chemistry.
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